発表論文　等

2025

　
1. 神林直哉
   "精密重合反応を基盤とした三次元構造制御"
   高分子学会会誌「高分子」"トッピクス", 2025, 74(11),615-616
   DOI:10.1295/kobunshi.74.11_615
   
2. Naoya Kanbayashi,* Kota Kawasaki, Kiyotaka Onitsuka*
   "Synthesis of a Precursor for Polymer Backbone Transformation via Quinoline N-Oxidation and Subsequent C-H Activation"
   Chem. Lett., 2025, 54, upaf193. DOI:10.1093/chemle/upaf193
   

        

3. Naoya Kanbayashi,* Aoto Nakajima, Taka-aki Okamura, Kiyotaka Onitsuka*
   "Orientation Control of Helical Poly(quinoline-2,3-diylmethylene) in Solution using a Tetraphenylporphyrin Scaffold"
   Macromolecule, 2025, 58, 8707-8715. DOI:10.1021/acs.macromol.5c01234
   Selected as "Cover"(Cover)

        

2024

1. Naoya Kanbayashi,* Sora Odagaki, Kiyotaka Onitsuka*
   "Side Chain Modification of π-Stacked Helical Poly(quinoline-2,3-diylemethylene) via Thiol-Ene Reaction"
   Polym. Chem., 2024, 15, 3563-3571. DOI:10.1039/D4PY00583J
   

        

2. Naoya Kanbayashi,* Sora Odagaki, Nano Kobayakawa, Hiroyuki Kato, Kiyotaka Onitsuka*
   "Direct Introduction of Cysteine Derivatives into the Chain-End of Helical Poly(Quinoline-2,3-diylmethylene)s: Densely Packed Monolayers on Au Substrates"
   Macromolecule, 2024, 57, 7787-7797. DOI:10.1021/acs.macromol.4c00561
   Selected as "Front cover"(Cover)

        

3. Jared M. Keever, Benjamin J. Pedretti, Zachary W. Brotherton, Jennifer Imbrogno, Yuki Kataoka, Jacob Baltzegar, Naoya Kanbayashi, Nathaniel A. Lynd*
   "Chain extension epoxide polymerization to well-defined block polymers using a N-Al Lewis pair catalyst"
   J. Polym. Sci., 2024, 62 2527-2538. DOI:10.1002/pol.20240002
   

2023

1. Naoya Kanbayashi,* Ryoga Yamamoto, Taka-aki Okamura, Kiyotaka Onitsuka*
   "Living Cyclocopolymerization via Alternating Insertion of Alkyl Isocyanide and Allene to the Organonickel Complex"
   Macromolecules, 2023, 56,8658-8665 DOI:10.1021/acs.macromol.3c01689
   

   

2. Naoya Kanbayashi,* Manami Narukawa, Kiyotaka Onitsuka*
   "Facile End-functionalization of Poly(quinolylene-2,3-methylene) Using the Terminal Palladium Complex: Thiocarbonylation through Formation of an Acyl-Palladium Complex at the Polymer Terminal"
   Macromol. Rapid. Commun., 2023, 44, 2300251. DOI:10.1002/marc.202300251
   

   

3. 神林直哉
   "精密重合反応を基盤とした新しいπスタック高分子の構築－"
   未来社会共創を目指す 研究シーズ集2023, 2023, 56. HP
4. Naoya Kanbayashi,* Miho Nishio, Taka-aki Okamura, Kiyotaka Onitsuka*
   "Synthesis of Helically π-Stacked Poly(quinolylene-2,3-methylene)s with Anthracene Derivatives at the Chain End: Intramolecular Energy Transfer Based on the π-Stacked Architecture"
   Polym. Chem., 2023, 14, 412-420. DOI:10.1039/D2PY01179D
   Selected as "OutsideFrontcover"(DOI: 10.1039/D3PY90011H)

        

2022

1. 神林直哉
   "πスタック型高分子の構造安定化とその形成機構の解明－"
   化学と工業（日本化学会誌）「Division Topics」, 2022, 75(11), 825. HP
2. Naoya Kanbayashi,* Kazuki Yamazaki, Miho Nishio, Kiyotaka Onitsuka*
   "Synthesis Methodology of End-Functionalized Poly(quinolylene-2,3-methylene)s: Living Cyclocopolymerization Using Aryl Palladium Initiators Conveniently Prepared from Versatile Aryl Halide"
   Macromolecules, 2022, 55,5027-5037 DOI:10.1021/acs.macromol.2c00826

   

3. Naoya Kanbayashi,* Yuki Kataoka, Taka-aki Okamura, Kiyotaka Onitsuka*
   "Stability Enhancement of π-Stacked Helical Structure using Substituents of Amino Acid Side Chain: Helix Formation via NucleationElongation Mechanism"
   J. Am. Chem. Soc, 2022, 144, 6080-6090. DOI:10.1021/jacs.2c01337

   

2021

1. Yuki Ishido, Naoya Kanbayashi,* Taka-aki Okamura, Kiyotaka Onitsuka*
   "Conformational Switch of Arylopeptide: Helix-helix Transition Based on Side Chain Solvation"
   Macromol. Rapid. Commun., 2021, 42, 2100250. DOI:10.1002/marc.202100250 Selected as "Frontcover"(DOI: 10.1002/marc.202170051)
   日本語概要
   

        

2020

1. Naoya Kanbayashi,* Marina Saegusa, Yuki Ishido, Taka-aki Okamura, Kiyotaka Onitsuka*
   "Synthesis of Optically Active Polymer Containing a Planar Phthalimide Backbone by Asymmetric Polymerization"
   Polym. Chem., 2020, 11, 6241-6250. (DOI:10.1039/D0PY01073A)
   Selected as "OutsideFrontcover"(DOI: 10.1039/D0PY90156C)
   日本語概要
   

        

2. 神林直哉
   "イソシアニドを基盤とした環化共重合反応－イソシアニドと不飽和炭化水素を組み合わせた環化重合反応への挑戦－"
   化学と工業（日本化学会誌）「飛躍する若手研究者」, 2020, 73(7), 580-581.
3. Yuki Kataokao, Naoya Kanbayashi,* Naoka Fujii, Taka-aki Okamura, Takeharu Haino, Kiyotaka Onitsuka*
   "Construction of Helically Stacked π-Electron Systems in Poly(quinolylene-2,3-methylene) Stabilized by Intramolecular Hydrogen Bonds"
   Angew. Chem. Int. Ed., 2020, 59, 10286-10291. (DOI:10.1002/anie.202002734)
   selected "Hot Paper", highlighted as "Frontspiece"(DOI: 10.1002/anie.202082661)
   日本語概要
   

        

4. Yuki Ishido, Naoya Kanbayashi,* Naoka Fujii, Taka-aki Okamura, Takeharu Haino, Kiyotaka Onitsuka*
   "Folding Control of Non-natural Glycopeptide Using Saccharide-coded Structural Information for Polypeptide"
   Chem. Commun., 2020, 56, 2767-2770. DOI:10.1039/C9CC10030J
   日本語概要
   

        

5. 神林直哉
   "まだ見ぬ新しい高分子合成反応を目指して"
   高分子学会会誌「高分子」"グローイングポリマー", 2020, 69(2),69.

2019

1. Naoya Kanbayashi,* Taka-aki Okamura, Kiyotaka Onitsuka*
   "Living Cyclocopolymerization Through Alternating Insertion of Isocyanide and Allene via Controlling the Reactivity of the Propagation Species: Detailed Mechanistic Investigation"
   J. Am. Chem. Soc, 2019, 141,15307-15317 DOI:10.1021/jacs.9b07431
   日本語概要
   

   

2. Naoya Kanbayashi*
   "Synthetic Approach for Optically Active Polymers Through the Combination of Asymmetric Chirogenic Polymerization and Post-polymerization Modification"
   Polym. J. , 2019, 51,1235-1247. Focus Review DOI:10.1038/s41428-019-0248-6 今月のハイライト論文に選出

   

3. Yuki Ishido, Naoya Kanbayashi,* Taka-aki Okamura, Kiyotaka Onitsuka*
   "Side-Chain-Driven Dual Structural System of Poly-Arylopeptide: Selective Helical Formation Derived from Aromatic Ring Flips on the Backbone"
   ACS Macro Lett., 2019, 8, 694-699. Cover selected DOI: 10.1021/acsmacrolett.9b00249
   日本語概要
   

        

   Naoya KANBAYASHI
   "Side-Chain-Driven Dual Structural System of Poly-Arylopeptide: Selective Helical Formation Derived from Aromatic Ring Flips on the Backbone"
   高分子学会会誌「高分子」"Hot Topics" selectted", 2019, 68(12),641
4. 神林直哉, 鬼塚清孝
   "金属－炭素結合へのイソシアニドと不飽和炭化水素の交互挿入反応に基づく環化共重合"
   高分子学会会誌「高分子」, 2019, 68(2),63-65
   

2018

1. Naoya Kanbayashi,* Jun Ikegami, Yuki Kataoka, Taka-aki Okamura, Kiyotaka Onitsuka*
   "Cyclocopolymerization Based on Alternating Insertions of Isocyanide and Allene Units into Palladium-Carbon Bond"
   Macromolecules, 2018, 51,6092-6098 DOI:10.1021/acs.macromol.8b01554

   

2. Yuki Kataoka, Naoya Kanbayashi,* Taka-aki Okamura, Kiyotaka Onitsuka*
   "Polymerization Based on Alternating Insertion of an Isocyanide and Alkyne into Palladium-Carbon Bonds"
   Polym. Chem., 2018, 9, 2797-2804 DOI: 10.1039/C8PY00381E

   

3. Naoya Kanbayashi,* Shingo Tokuhara, Tomoko Sekine, Yuki Kataoka, Taka-aki Okamura, Kiyotaka Onitsuka*
   "Synthesis of helical polyisocyanides bearing aza-crown ether groups as pendant"
   J. Polym. Sci., Part A: Polym. Chem., 2018, 56,496-504 DOI: 10.1002/pola.28919

   

4. 鬼塚清隆, 岡村高明, 神林直哉
   "研究室紹介ー北から南からー "
   Organometallic News, 2018, 3,97-98 PDF

2017

1. Yuki Ishido, Naoya Kanbayashi,* Taka-aki Okamura, Kiyotaka Onitsuka*
   "Synthesis of Non-natural Helical Polypeptide via Asymmetric Polymerization and Reductive Cleavage of N-O Bond"
   Macromolecules, 2017, 50, 5301-5307. DOI: 10.1021/acs.macromol.7b01426

   

2. 神林 直哉
   "不斉重合反応を基盤とする光学活性高分子の新規合成法の開発
   高分子論文集 (高分子科学・工学のニューウェーブ), 2017, DOI: 10.1295/koron.2017-0027
3. Taka-aki Okamura*, Toshihisa Kaga, Satoshi Yamashita, Ryosuke Furuya, Kiyotaka Onitsuka
   "Snapshot of Oxidation of Thiolate by Diiodine: Stabilization of Intermadiate by NH···S Hydrogen Bonds"
   J. Org.Chem., 2017, 82, 10187-10192. DOI: 10.1021/acs.joc.7b00160

   

4. Naoya Kanbayashi*, Sou Miyamoto, Yuki Ishido, Taka-aki Okamura, Kiyotaka Onitsuka*
   "Post-Polymerization Modification of the Side Chain in Optically Active Polymer by Thiol-Ene Reaction"
   Polym. Chem., 2017, 8, 985-994. Front Cover selected DOI: 10.1039/C6PY01946C イギリス化学会のNEWSで紹介されました．HP（2017.3.23）

        

2016

1. Naoya Kanbayashi*, Kazuki Hosoda, Taka-aki Okamura, Sadahito Aoshima, Kiyotaka Onitsuka*
   "Enantio- and Diastereoselective Polymerization: Asymmetric Allylic Alkylation Catalyzed by a Planar-chiral Cp′Ru Complex"
   Polym. Chem., 2016, 7, 3691-3699. DOI: 10.1039/C6PY00484A

   

2. Naoya Kanbayashi*, Arisa Yamazawa, Koichiro Takii, Taka-aki Okamura, Kiyotaka Onitsuka*
   "Planar-chiral Cyclopentadienyl Ruthenium Catalyzed Regio- and Enantioselective Asymmetric Allylic Alkylation of Silyl Enolates under Unusually Mild Condition"
   Adv. Synth. Catal., 2016, 258, 555-560. DOI: 10.1002/adsc.201500970 SYNFACTS selected (Synfacts 2015, 11, 1079.) DOI: 10.1055/s-0035-1562073

   

2015

1. Naoya Kanbayashi*, Taka-aki Okamura, Kiyotaka Onitsuka*
   "New Synthetic Approach for Optically Active Polymer Bearing Chiral Cyclic Architecture: Combination of Asymmetric Allylic Amidation and Ring-closing Metathesis Reaction"
   Macromolecules, 2015, 48, 8437-8444. DOI: 10.1021/acs.macromol.5b02067

   

2. Naoya Kanbayashi*, Kazuki Hosoda, Masanori Kato, Koichiro Takii, Taka-aki Okamura, Kiyotaka Onitsuka*
   "Enantio- and diastereoselective asymmetric allylic alkylation catalyzed by planar-chiral cyclopentadienyl ruthenium complex"
   Chem. Commun., 2015, 10895-10898. DOI: 10.1039/C5CC02414E SYNFACTS selected (Synfacts 2015, 11(10), 1079.) DOI: 10.1055/s-0035-1560225

   

　

2014

1. Naoya Kanbayashi*, Taka-aki Okamura, Kiyotaka Onitsuka
   "New Method for Asymmetric Polymerization: Asymmetric Allylic Substitution Catalyzed by a Planar-Chiral Ruthenium Complex"
   Macromolecules, 2014, 47, 4178-4185. DOI: 10.1021/ma5008623

   

2013

1. Naoya Kanbayashi, Kazuhiro Takenaka, Taka-aki Okamura, Kiyotaka Onitsuka*
   "Asymmetric Auto-Tandem Catalysis with a Planar-Chiral Ruthenium Complex: Sequential Allylic Amidation and Atom-Transfer Radical Cyclization"
   Angew. Chem., Int. Ed., 2013, 52, 4897-4901.
   DOI: 10.1002/anie.201300485 SYNFACTS selected (Synfacts 2013, 9, 0760.)

   

2012

1. Koichiro Takii, Naoya Kanbayashi, Kiyotaka Onitsuka*
   "Modular synthesis of optically active lactones by Ru-catalyzed asymmetric allylic carboxylation and ring-closing metathesis reaction"
   Chem. Commun., 2012, 48, 3872-3874.
   DOI: 10.1039/C2CC18137A SYNFACTS selected (Synfacts 2012, 8, 0634.)

   

2011

1. Naoya Kanbayashi, Kiyotaka Onitsuka*
   "Ruthenium-Catalyzed Regio- and Enantioselective Allylic Substitution with Water: Direct Synthesis of Chiral Allylic Alcohols"
   Angew. Chem., Int. Ed., 2011, 50, 5197-5199.
   DOI: 10.1002/anie.201101078 SYNFACTS selected (Synfacts 2011, 8, 0876.)

   

2010

1. Naoya Kanbayashi, Kiyotaka Onitsuka
   "Enantioselective Synthesis of Allylic Esters via Asymmetric Allylic Substitution with Metal Carboxylates Using Planar-Chiral Cyclopentadienyl Ruthenium Catalysts"
   J. Am. Chem. Soc., 2010, 132, 1206-1207.
   DOI: 10.1021/ja908456b SYNFACTS selected (Synfacts 2010, 4, 0452.)

   

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