Sterically Congested LLX-Type PNSi Tridentate Ligands for Iridium-Catalyzed C(sp3)–H Borylation
Takeru Torigoe,* Akika Kon, Kairi Mine, Yoichiro Kuninobu, Toshimichi Ohmura*
Angew. Chem. Int. Ed., 2025, e202515538. 10.1002/anie.202515538
Boronyl-Group-Assisted Decatungstate-Catalyzed Benzylic C(sp3)−H Alkylation
Hui Jiang, Takeru Torigoe,* Yoichiro Kuninobu*
Org. Lett., 2024, 26, 4853-4856. 10.1002/ejoc.202301015
5-Ammonium-4,4-dimethylvaleryl (Amv) Group: Generation from Acryloyl Group through Decatungstate-Catalyzed C(sp3)−H Addition and Removal by Base-Triggered Cyclization
Jizhou Song, Takeru Torigoe,* Yoichiro Kuninobu*
Eur. J. Org. Chem., 2023, 26, e202301015. 10.1002/ejoc.202301015
Decatungstate-Catalyzed C(sp3)–H Alkylation of a Val Residue Proximal to the N-Terminus Controlled by an Electrostatic Interaction
Jizhou Song, Takeru Torigoe,* Yoichiro Kuninobu*
Org. Lett., 2023, 25, 3708-3712. 10.1021/acs.orglett.3c01154
3-Position-Selective C–H Trifluoromethylation of Pyridine Rings Based on Nucleophilic Activation
Ryuhei Muta, Takeru Torigoe, Yoichiro Kuninobu*
Org. Lett., 2022, 24, 8218-8222. 10.1021/acs.orglett.2c03327
Iridium-catalyzed C(sp3)–H Borylation Using Silyl-Bipyridine Pincer Ligands
Ryohei Kawazu, Takeru Torigoe,* Yoichiro Kuninobu*
Angew. Chem. Int. Ed., 2022, 61, e202202327. 10.1002/anie.202202327
Control of Site-Selectivity in Hydrogen Atom Transfer by Electrostatic Interaction: Proximal-Selective C(sp3)–H Alkylation of 2-Methylanilinium Salts Using a Decatungstate Photocatalyst
Jialin Zeng, Takeru Torigoe,* Yoichiro Kuninobu*
ACS Catal., 2022, 12, 3058-3062. 10.1021/acscatal.2c00278
[Commentary]
歪みのないC(sp3)–Si結合の酸化的付加
鳥越尊
Organometallic News, 2021, 88.
Intramolecular Addition of a Dimethylamino C(sp3)–H Bond across C–C Triple Bonds using IrCL(DTBM-SEGPHOS)(ethylene) Catalyst: Synthesis of Indoles from 2-Alkynyl-N-methylanilines
Toshimichi Ohmura,* Kaito Yagi, Takeru Torigoe, Michinori Suginome*
Synthesis, 2021, 53, 3057-3064. 10.1055/a-1511-1025
Regioselective C–H Trifluoromethylation of Aromatic Compounds by Inclusion in Cyclodextrins
Xu Lu, Ryohei Kawazu, Jizhou Song, Yusuke Yoshigoe, Takeru Torigoe, Yoichiro Kuninobu*
Org. Lett., 2021, 23, 4327-4331. 10.1021/acs.orglett.1c01259
Manganese/Bipyridine-catalyzed Non-directed C(sp3)-H Bromination Using NBS and TMSN3
Kumar Sneh, Takeru Torigoe, Yoichiro Kuninobu*
Beilstein J. Org. Chem., 2021, 17, 885-890. 10.3762/bjoc.17.74
Regioselective C(sp3)–H Alkylation of Fructopyranose Derivative by 1,6 HAT
Yanru Li, Shoto Miyamoto, Takeru Torigoe, Yoichiro Kuninobu*
Org. Biomol. Chem., 2021, 19, 3124-3127. 10.1039/D1OB00326G
Urea-accelerated Iridium-catalyzed 2-Position-selective C-H Borylation of Indole Derivatives
Jie Wang, Takeru Torigoe, Yoichiro Kuninobu*
Chem. Lett., 2021, 50, 808-811. 10.1246/cl.200939
[Review]
Regioselective C-H Trifluoromethylation of Heteroaromatic Compounds
Yoichiro Kuninobu,* Takeru Torigoe
Bull. Chem. Soc. Jpn., 2021, 94, 532-541. 10.1246/bcsj.20200302
[Commentary]
有機溶媒がいらない!? －固体状態での高効率クロスカップリング反応
鳥越尊, 國信洋一郎
化学, 2020, 75, 64-65.
[Review]
Resent Progress on Transition Metal-catalysed Regioselective C–H Transformations Based on Noncovalent Interactions
Yoichiro Kuninobu,* Takeru Torigoe
Org. Biomol. Chem., 2020, 18, 4126-4134. 10.1039/D0OB00703J
Iridium-Catalyzed ortho-C–H Borylation of Thioanisole Derivatives Using Bipyridine-Type Ligand
Jialin Zeng, Morio Naito, Takeru Torigoe, Masahiro Yamanaka,* Yoichiro Kuninobu*
Org. Lett., 2020, 22, 3485-3489. 10.1021/acs.orglett.0c00946
Copper-Catalyzed Tertiary Alkylative Cyanation for the Synthesis of Cyanated Peptide Building Blocks
Naoki Miwa, Chihiro Tanaka, Syo Ishida, Goki Hirata, Jizhou Song, Takeru Torigoe, Yoichiro Kuninobu,* Takashi Nishikata*
J. Am. Chem. Soc., 2020, 142, 1692-1697. 10.1021/jacs.9b11349
Iridium-Catalyzed C(sp3)–H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans
Toshimichi Ohmura,* Satoshi Kusaka, Takeru Torigoe, Michinori Suginome*
Adv. Synth. Catal., 2019, 361, 4448-4453. 10.1002/adsc.201900749
2-Position-Selective Trifluoromethylthiolation of Six-Membered Heteroaromatic Compounds
Ryuhei Muta, Takeru Torigoe, Yoichiro Kuninobu*
Org. Lett., 2019, 21, 4289-4292. 10.1021/acs.orglett.9b01474
Hydrogen-Bond-Controlled Formal Meta-Selective C–H Transformations and Regioselective Synthesis of Multisubstituted Aromatic Compounds
Jie Wang, Takeru Torigoe, Yoichiro Kuninobu*
Org. Lett., 2019, 21, 1342-1346. 10.1021/acs.orglett.9b00030
Asymmetric Cycloisomerization of o-Alkenyl-N-methylanilines to Indolines through Iridium-Catalyzed C(sp3)–H Addition to Carbon–Carbon Double Bonds
Takeru Torigoe, Toshimichi Ohmura,* Michinori Suginome*
Angew. Chem. Int. Ed., 2017, 56, 14272–14276. 10.1002/anie.201708578
Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)–H Borylation at the Methyl Group on Silicon
Takeru Torigoe, Toshimichi Ohmura,* Michinori Suginome*
J. Org. Chem., 2017, 82, 2943–2956. 10.1021/acs.joc.6b02917
Iridium-Catalyzed Intramolecular Methoxy C–H Addition to Carbon–Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes
Takeru Torigoe, Toshimichi Ohmura,* Michinori Suginome*
Chem. Eur. J., 2016, 22, 10415–10419. 10.1002/chem.201602152
A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp3)–H Borylation and Conversion to Functionalized Siloxanes
Toshimichi Ohmura,* Ikuo Sasaki, Takeru Torigoe, Michinori Suginome*
Organometallics, 2016, 35, 1601–1603. 10.1021/acs.organomet.6b00316
Iridium-Catalysed Borylation of Sterically Hindered C(sp3)–H bonds: Remarkable Rate Acceleration by a Catalytic Amount of Potassium tert-Butoxide
Toshimichi Ohmura,* Takeru Torigoe, Michinori Suginome*
Chem. Commun., 2014, 50, 6333–6336. 10.1039/C4CC01262C
Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium Catalyzed C(sp3)–H Borylation
Toshimichi Ohmura,* Takeru Torigoe, Michinori Suginome*
Organometallics, 2013, 32, 6170–6173. 10.1021/om400900z
Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes
Toshimichi Ohmura,* Takeru Torigoe, Michinori Suginome*
J. Am. Chem. Soc., 2012, 134, 17416–17419. 10.1021/ja307956w
