Achievement

論文

2024年

＊Mechanofluorochromic properties of 1,4-diphenylanthracene derivatives with hypsochromic shift
Fumihiro Kannen, Tadatoshi, Adachi, Manato Nishimura, Kenji Yoza, Takahiro Kusukawa*
Molecules 2024, 29, 407

2023年

＊Mechanofluorochromic properties of 1-phenylanthracene derivatives with extremely simple structures
Fumihiro Kannen, Manato Nishimura, Kenji Yoza, Takahiro Kusukawa*
Tetrahedron, 2023, 149, 133710

＊Pnictogen-bridged diphenyl sulfones as photoinduced pnictogen bond forming emission motifs
Toshiki Fujii, Takahiro Kusukawa, Hiroaki Imoto, Kensuke Naka
Chem. Eur. J., 2023, 29, e202202572

2022年

＊Highly-selective recognition of dicarboxylic acid using 9-(diphenylmethylene)fluorene-based diamidine
Takahiro Kusukawa*, Shinya Tsujimoto, Mayuko Nakamura
Tetrahedron, 2022, 129, 133139

＊Mechnofluorochromic properties of N-alkyl amide anthracene derivatives
Takahiro Kusukawa*, Seiji Shibata, Fumihiro Kannen and Kenji Yoza
Tetrahedron, 2022, 111, 132735

＊Preferential solvation of meso-methyl BODIPYs with pyridine via pseudo-hydrogen-bonds
Mitsuhiko Morisue, Miho Kawanishi, Takahiro Kusukawa
Phys. Chem. Chem. Phys. 2022, 24, 3478-3485

2021年

＊Carboxylic acid recognition of an N-ethyl-substituted diamidine having a diphenylnaphthalene unit in competing protic solvents
Takahiro Kusukawa*, Keisuke Matoba, Yuki Hoshihara, Syugo Tanaka, Akane Nakajima
Tetrahedron, 2021, 96, 132373

＊Directional supramolecular polymerization in a dynamic microsolution: A linearly moving polymer’s end striking monomers
Shota Matoba, Chisako Kanzaki, Kae Yamashita, Takahiro Kusukawa, Gaku Fukuhara,Tetsuo Okada, Tetsuya Narushima, Hiromi Okamoto, Munenori Numata
J. Am. Chem. Soc. 2021,143, 8731–8746

＊Carboxylic acid recognition of a tetraamidine having a tetraphenylethylene unit based on aggregation-induced emission
Takahiro Kusukawa*, Yuki Hoshihara, Kazuki Yamana
Tetrahedron, 2021, 92, 132254

＊Recognition of dicarboxylic acids and diphosphonic acids using anthracene-based diamidine: formation of amidinium-carboxylate and amidinium-phosphonate salt bridges in a protic solvent
Takahiro Kusukawa*, Keita Nakaguchi, Saya Nishimura, Akane Nakajima
Supramol. Chem. 2021, 33, 43-52

＊Charge-transfer-adaptable double-strand formation of porphyrin–BODIPY–porphyrin triad
Mitsuhiko Morisue, Miho Kawanishi, Takahiro Kusukawa
ChemPhotoChem 2021, 5, 538-544

＊Dinuclear rhombic copper(I) iodide complexes with rigid bidentate arsenic ligands
Ryosuke Kobayashi, Hyota Kihara, Takahiro Kusukawa, Hiroaki Imoto, Kensuke Naka
Chem. Lett. 2021, 50, 382-385

＊Recognition of carboxylic acids and phosphonic acids using 1,8-diphenylnaphthalene- based diguanidine
Takahiro Kusukawa*, Ryosuke Mura, Masashi Ooe, Ryuki Sumida, Ayaka Nakagawa
Tetrahedron 2021, 77, 131700

＊Crystal polymorphism-dependent fluorescence of fluoroarene-substituted anthracene derivatives
Takahiro Kusukawa*, Fumihiro Kannen, Yusuke Kojima, Kenji Yoza
Chem. Lett. 2021, 50, 31-34

2020年

＊Biobased poly(itaconic acid-co-10-hydroxyhexylitaconic acid)s: synthesis and thermal characterization
Yuji Aso, Mei Sano, Ryoki Yada, Tomonari Tanaka, Takashi Aoki, Hitomi Ohara, Takahiro Kusukawa, Keiji Matsumoto, Kazuhito Wada
Materials 2020, 13, 2707

＊Microbial screening based on the Mizoroki-Heck reaction permits exploration of hydroxyhexylitaconic-acid-producing fungi in soils
Mei Sano, Ryoki Yada; Yusuke Nomura; Tomonari Tanaka; Hitomi Ohara; Yuji Aso; Takahiro Kusukawa; Hiroshi Ando; Keiji Matsumoto; Kazuhito Wada
Microorganisms 2020, 8, 648

＊Dipyrrin complexes of borasiloxane silanols with adaptive hydrogen-bonded conformations in the crystal and in solution states
Mitsuhiko Morisue, Takahiro Kusukawa, Seiji Watase
Eur. J. Inorg. Chem. 2020, 2020,1885-1893

＊Synthesis of an anthracene-based diguanidine and its recognition of carboxylic acids and phosphonic acids
Takahiro Kusukawa∗, Ryosuke Mura, Yasuhiro Ohtagaki, Masashi Ooe
Tetrahedron 2020, 76, 131065

2019年

＊Mechanofluorochromic properties of 1,8-diphenylanthracene derivatives
Takahiro Kusukawa*, Yusuke Kojima, Fumihiro Kannen
Chem. Lett. 2019, 48, 1213-1216

＊Carboxylic acid recognition of diamidine having a fluorescent 1,8-diphenylanthracene unit and its detection of amidinium-carboxylate and amidinium formation
Takahiro Kusukawa∗, Hiroki Aramoto, Takehiro Umeda, Yusuke Kojima
Tetrahedron 2019, 75, 1293-1305

2018年

＊A Turn-on Fluorescence Sensor for Dicarboxylic Acids Based on Aggregation-　induced Emission
Takahiro Kusukawa,* Eyob Ashenafi Tessema, and Yuki Hoshihara
Chem. Lett. 2018, 47, 1395-1398

＊Turn-on fluorescence sensor for mono- and di-phosphonic acid derivatives using anthracene-based diamidine and its detection of amidinium-phosphonate and amidinium formation
Takahiro Kusukawa*, Hitoshi Nagano, Keita Nakaguchi, Shota Takeshita, Yuya Harumoto
Tetrahedron 2018, 74, 465-476

2017年

＊Dicarboxylic Acid Recognition of 1,8-Bis(N,N’-diethylamidino)anthracne: NMR, X-ray, ESI-mass and Fluorescence Analyses of Dicarboxylic Acid Binding Complexes
Takahiro Kusukawa*, Kouta Inoue Hiroaki Obata, Ryosuke Mura
Tetrahedron 2017, 73, 661-670

2016年

＊Enhancement of the catalytic activity of chiral H8-BINOL titanium complexes by introduction of sterically demanding groups at the 3-position
Yasuki Hayashi, Nobuaki Yamamura, Takahiro Kusukawa, Toshiro Harada
Chem. Eur. J. 2016, 22, 12095-12105

2015年

＊Formation of discrete ladders and a macroporous xerogel film by the zipperlike dimerization of meso–meso-linked zinc(II) porphyrin arrays with di(pyrid-3-yl)acetylene
Kohei Kose, Jin Motoyanagi, Takahiro Kusukawa, Atsuhiro Osuka, Akihiko Tsuda
Angew. Chem. Int. Ed. 2015, 54, 8673-8678
2014年

＊Fluorescent detection of amidinium-carboxylate and amidinium formation using a 1,8-diphenylnaphthalene-based diamidine: dicarboxylic acid recognition with high fluorescence efficiency
Takahiro Kusukawa*, Syugo. Tanaka, Kouta Inoue
Tetrahedron, 2014, 70, 4049-4056
2013年

＊Four-component assembly in the crystalline state driven by amidinium-carboxylate salt bridge formation from an aqueous solution
Takahiro Kusukawa*, Kazuya Matsumoto, Hajime Nakamura, Wataru Iizuka, Keisuke Toyama, Shota Takeshita
Org. Biomol. Chem., 2013, 11, 3692-3698

＊Observation of a hydrogen-bonded 3D structure of crystalline glycerol
Takahiro Kusukawa*, Genki Niwa, Takato Sasaki, Ryosuke Oosawa, Wataru Himeno, Masahiro Kato*
Bull. Chem. Soc. Jpn. 2013, 86, 351-353

＊A triangular prismatic hexanuclear iridium(III) complex bridged by flavin analogues showing reversible redox processes
Yuji Inui, Motoo Shiro, Takahiro Kusukawa, Shunichi Fukuzumi, Takahiko Kojima
Dalton Trans. 2013, 42, 2773-2778

2012年

＊Fluorescent detection of amidinium-carboxylate and amidinium formation using anthracene-based diamidine: an application for the analysis of dicarboxylic acid binding
Takahiro Kusukawa*, Keisuke Toyama, Shota Takeshita, Syugo Tanaka
Tetrahedron 2012, 68, 9973-9981

＊Formation and characterization of water-soluble hetero capsules derived from multiple ionic interactions
Takahiro Kusukawa*, Chikako katano, Chizuru Kim
Tetrahedron, 2012, 68, 1492-1501

2010年

＊Alkylative carbocyclization of ω-iodoalkynyl tosylates with alkynyllithium compounds through a carbenoid-chain process leadung to (1-iodoprop-2-ynylidene)tetrahydrofurans and -cycloprpanes
Toshiro Harada, Daisuke Imaoka, Chie Kitano, Takahiro Kusukawa
Chem. Eur. J. 2010, 16, 9164-9174

2008年

＊A discrete supramolecular conglomerate composed of two saddle-distorted zinc(II)-phthalocyanine complexes and a doubly protonated porphyrin with saddle distortion undergoing efficient photoinduced electron transfer
Takahiko Kojima, Tatsuhiko Honda, Kei Ohkubo, Motoo Shiro, Takahiro Kusukawa, Takamitsu Fukuda, Nagao Kobayashi, Shunichi Fukuzumi
Angew. Chem. Int. Ed. 2008, 47, 6712

2008年

＊Development of highly enantioselective oxazaborolidinone catalysts for the reactions of acyclic α,β-unsaturated ketones
Toshiro Harada, Takahiro Kusukawa
Synlett, 2007, 1823-1835

2005年

＊High facial selectivity observed in amine coordination to chiral oxazaborolidinone
Toshiro Harada, Yuuki Yamamoto, Takahiro Kusukawa
Chem. Commun. 2005, 859-861

2003年

＊Phenylenebis(ethynyl)-tethered bis-BINOL ligands for enantioselective catalyst based on dimeric Ti(IV) aggregate
Toshiro Harada, Yuki Hiraoka, Takahiro Kusukawa, Yasuhisa Marutani, Shinichro Matsui, Masashi Nakatsugawa, Koso Kanda
Org. Lett. 2003, 5, 5059-5062

2005年

＊Endohedral clusterization of ten water molecules into a “molecular ice” within the hydrophobic pocket of a self-assembled cage
Michito Yoshizawa, Takahiro Kusukawa, Masaki Kawano, Takashi Ohhara, Ichiro Tanaka, Kazuo Kurihara, Nobuo Niimura, Makoto Fujita
J. Am. Chem. Soc. 2005, 127, 2798-2799

2004年

＊Finite, spherical coordination networks that self-organize from 36 small components
Masahide Tominaga, Keisuke Suzuki, Masaki Kawano, Takahiro Kusukawa, Tomoji Ozeki, Shigeru Sakamoto, Kentaro Yamaguchi, Makoto Fujita
Angew. Chem. Int. Ed. 2004, 43, 5621-5625

＊A palladium(II)-clipped aromatic sandwich
Kazuhisa Kumazawa, Yoshinori Yamanoi, Michito Yoshizawa, Takahiro Kusukawa, Makoto Fujita
Angew. Chem. Int. Ed. 2004, 43, 5936-5940

＊A circular tris[2]catenane from molecular figure of eight
Akiko Hori, Ken-ichi Yamashita, Takahiro. Kusukawa, Akihiko Akasaka, Kumar Biradha, Makoto Fujita
Chem. Commun. 2004, 1798-1799

＊Complementary multicomplexation of desymmetrized 2,2’-bipyridine ligands on square planar Pd(II) centers
Masahide Tominaga, Takahiro Kusukawa, Shigeru Sakamoto, Kentaro Yamaguchi, Makoto Fujita
Chem. Lett. 2004, 33, 794-795

＊Phenyl trifluorovinyl sulfide: a radical acceptor for preparation of gem-difluoromethylene compounds
Takashi Okano, Masayaki Chokai, Makiko Hiraishi, Michito Yoshizawa, Takahiro Kusukawa, Makoto Fujita
Tetrahedron 2004, 60, 4031-4035

2003年

＊Multicomponent assembly of a pyrazine-pillared coordination cage that selectively binds planar guests by intercalation
Kazuhisa Kumazawa, Kumar Biradha, Takahiro Kusukawa, Takashi Okano, Makoto Fujita
Angew. Chem. Int. Ed. 2003, 42, 3909-3913

＊The polar effect on the regiochemistry of nucleophilic substitution of trifluoromethylated π-allylpalladium complex
Takashi. Okano, Hiroyoshi Matsubara, Takahioro Kusukawa, Makoto Fujita
J. Organomet. Chem. 2003, 676, 43-48

＊Pd^II-directed dynamic assembly of a dodecapyridine ligand into end-capped and open tubes: the importance of kinetic control in self-assembly
Shohei Tashiro, Masahide Tominaga, Takahiro Kusukawa, Masaki Kawano, Shigeru Sakamoto, Kentaro Yamaguchi, Makoto Fujita
Angew. Chem. Int. Ed. 2003, 42, 3267-3270

＊Remarkable acceleration of Diels-Alder reactions in a self-assembled coordination cage
Takahiro Kusukawa, Tatsuya Nakai, Takashi Okano, Makoto Fujita
Chem. Lett. 2003, 32, 284-285

2002年

＊Self-assembled M₆L₄–type coordination nanocage with 2,2’-bipyridine ancillary ligands. Facile crystallization and X-ray analysis of shape-selective enclathration of neutral guest in the cage
Takahiro Kusukawa, Makoto Fujita
J. Am. Chem. Soc. 2002, 124, 13576-13582

＊Electrochemically driven clathration/declathration of ferrocene and its derivatives by a nanometer-sized coordination cage
Wei-Yin Sun, Takahiro Kusukawa, Makoto Fujita
J. Am. Chem. Soc. 2002, 124, 11570-11571

＊Synthesis of optically active trifluoromethylated indolizidine derivatives via stereoselective radical cyclization
Takashi Okano, Masataka Fumoto, Takahiro Kusukawa, Makoto Fujita
Org. Lett. 2002, 4, 1571-1573

＊Copper(I)-Catalyzed Addition of Trifluoromethylated Benzyl Radicals Derived from Aryltrifluoroethyl Bromides to Terminal Olefins
Takashi Okano, Hirokazu Sugiura, Masataka Fumoto, Hiroyoshi Matsubara, Takahiro Kusukawa, Makoto Fujita
J. Fluorine Chem. 2002, 114, 91-98

＊Cavity-directed, highly stereoselective [2+2] photodimerization of olefins within self-assembled coordination cages
Michito Yoshizawa, Yoshihisa Takeyama, Takahiro Kusukawa, Makoto Fujita
Angew. Chem. Int. Ed. 2002, 41, 1347-1349

2001年

＊Cavity-Directed Synthesis of Labile Silanol Oligomers within Self-Assembled Coordination Cages
Michito Yoshizawa, Takahiro Kusukawa*, Makoto Fujita*, Shigeru Sakamoto, Kentaro Yamaguchi
J. Am. Chem. Soc. 2001, 123, 10454-10459

＊DOSY Study on Dynamic Catenation: Self-Assembly of a [3]Catenane as a Meta-Stable Compound from Twelve Simple Components
Akiko Hori, Kazuhisa Kumazawa, Takahiro Kusukawa, Dillip Kumar Chand, Makoto Fujita, Shigeru Sakamoto, Kentaro Yamaguchi
Chem. Eur. J. 2001, 7, 4142-4149

＊Molecular paneling by coordination: An M₁₅L₆ hexahedral molecular capsule having clefts for reversible guest inclusion
Kazuhiko Umemoto, Hitoshi Tsukui, Takahiro Kusukawa, Kumar Biradha, Makoto Fujita
Angew. Chem. Int. Ed. 2001, 40, 2620-2622

＊Characterization of encapsulating supramolecules by using CSI-MS with ionization-promoting reagents
Shigeru Sakamoto, Michito Yoshizawa, Takahiro Kusukawa, Makoto Fujita, Kentaro Yamaguchi
Org. Lett. 2001, 3, 1601-1604

＊Probing guest geometry and dynamics through host-guest interactions
Takahiro Kusukawa, Michito Yoshizawa, Makoto Fujita
Angew. Chem. Int. Ed. 2001, 40, 1879-1884

＊Dynamic assembly of coordination boxes from (en)Pd(II) unit and a rectangular panel-like ligand: NMR, CSI-MS, and X-ray studies
Yoshinori Yamanoi, Youichi Sakamoto, Takahiro Kusukawa, Makoto Fujita, Shigeru Sakamoto, Kentaro Yamaguchi
J. Am. Chem. Soc. 2001, 123, 980-981

2000年

＊Ship-in-a-bottle synthesis of otherwise labile cyclic trimers of siloxanes in a self-assembled coordination cage
Michito Yoshizawa, Takahiro Kusukawa, Makoto Fujita, Kentaro Yamaguchi
J. Am. Chem. Soc. 2000, 122, 6311-6312

＊Wacker oxidation in an aqueous phase through the reverse phase-tansfer catalysis of a self-assembled nanocage
Hirokazu Ito, Takahiro Kusukawa*, Makoto Fujita*
Chem. Lett. 2000, 29, 598-599

＊Hydrophobic assembling of a coordination nanobowl into a dimeric capsule which can accomodate up to six large organic molecules
Shu-Yan Yu, Takahiro Kusukawa, Kumar Biradha, Makoto Fujita
J. Am. Chem. Soc. 2000, 122, 2665-2666

1999年

＊“Ship-in-a-bottle” formation of stable hydrophobic dimers of cis-azobenzene and -stilbene derivatives in a self-assembled coordination nanocage
Takahiro Kusukawa, Makoto Fujita
J. Am. Chem. Soc. 1999, 121, 1397-1398

1998年

＊A tris-phenylphenol N₈O₃ schiff-base cryptand: Structural characterization and fluorescence titration for lanthanide coordination
Shu-Yan Yu, Biao Wu, Xiao-Jian Yang, Wen-Jian Zhang, Xintao Wu, Takahiro Kusukawa
J. Phys. Org. Chem. 1998, 11, 903-911

＊Encapsulation of large, neutral molecules in a self-assembled nanocage incorporating six palladium(II) ions
Takahiro Kusukawa, Makoto Fujita
Angew. Chem. Int. Ed. Engl. 1998, 37, 3142-3144

＊A thermally switchable molecular lock. The guest-templated synthesis of a kinetically stable nanosized cage
Fumiaki Ibukuro, Takahiro Kusukawa, Makoto Fujita
J. Am. Chem. Soc. 1998, 120, 8561-8562

＊Photochemical functionalizations of C₆₀ with phenylpolysilanes
Takahiro Kusukawa, Wataru Ando
J. Organomet. Chem. 1998, 559, 11-22

＊Self-assembly of nanometer-sized macrotricyclic complexes from ten small component molecules
Makoto Fujita, Shu-Yan Yu, Takahiro Kusukawa, Hidenori Funaki, Katsuyuki Ogura, Kentaro Yamaguchi
Angew. Chem. Int. Ed. Engl. 1998, 37, 2082-2085

＊Substituents effects on the addition of silyllithium and germyllithium to C₆₀
Takahiro Kusukawa, Wataru Ando
J. Organomet. Chem. 1998, 561, 109-120

1997年

＊Photochemical reactions of oligosilanes with C₆₀
Takahrio Kusukawa, Wataru Ando
Organometallics 1997, 16, 4027-4029

＊Reactions of a C₆₀-substituted benzotetrasilacyclohexane with bromine
Takahiro Kusukawa, Kenichi Ohkubo, Wataru Ando
Organometallics 1997, 16, 2746-2747

1996年

＊Reactions of silyllithium with C₆₀: Isolation and X-ray crystallographic characterization of an unusual bissilylated-C₆₀ adduct
Takahiro Kusukawa, Wataru Ando
Angew. Chem. Int. Ed. Engl. 1996, 35, 1315-1317

＊Photochemical functionalization of C₆₀ with cyclosilanes and cyclogermane
Takahiro Kusukawa, Akihiko Shike, Wataru Ando
Tetrahedron 1996, 52, 4995-5005

＊Co(salen)-catalyzed tert-Butyl hydroperoxide oxidation of tert-Butylphenols bearing an unsaturated side chain
Kazushige Maruyama, Takahiro Kusukawa, Takahiro Mashino, Akira Nishinaga
J. Org. Chem. 1996, 61, 3342-3349

1995年

＊Photochemical additions of cyclo-(Ar₂Si)₄ and (Ar₂Ge)₄ to C₆₀
Takahiro Kusukawa, Yoshio Kabe, Wataru Ando
Organometallics, 1995, 14, 2142-2144

＊Palladium catalyzed disilane metathesis reaction of 1,2-disilacyclobutanes
Takahiro Kusukawa, Yoshio Kabe, Bernt Nestler, Wataru Ando
Organometallics 1995, 14, 2556-2564

1994年

＊Unusual rearrangement in the photochemical addition of bis(alkylidene)disilacyclobutane to C₆₀
Takahiro Kusukawa, Yoshio Kabe, Tomoki Erata, Bernt Nestler, Wataru Ando
Organometallics 1994, 13, 4186-4188

1993年

＊Transition metal catalyzed reaction of peralkylated 3,4-bis(alkylidene)-1,2-disilacyclobutane
Takahiro Kusukawa, Yoshio Kabe, Wataru Ando
Chem. Lett. 1993, 22, 985-988

1991年

＊Cobalt schiff base complex catalyzed dehydrogenation of amines with t-butyl hydroperoxide
Kazushige Maruyama, Takahiro Kusukawa, Yoshihiko Higuchi, Akira Nishinaga
Chem. Lett. 1991, 20, 1093-1096