5-Ammonium-4,4-dimethylvaleryl (Amv) Group: Generation from Acryloyl Group through Decatungstate-Catalyzed C(sp3)−H Addition and Removal by Base-Triggered Cyclization
Jizhou Song, Takeru Torigoe, and Yoichiro Kuninobu
Eur. J. Org. Chem., 2023, 26, e202301015. 10.1002/ejoc.202301015
Decatungstate-Catalyzed C(sp3)–H Alkylation of a Val Residue Proximal to the N-Terminus Controlled by an Electrostatic Interaction
Jizhou Song, Takeru Torigoe, and Yoichiro Kuninobu
Org. Lett., 2023, 25, 3708-3712. 10.1021/acs.orglett.3c01154
3-Position-Selective C–H Trifluoromethylation of Pyridine Rings Based on Nucleophilic Activation
Ryuhei Muta, Takeru Torigoe, and Yoichiro Kuninobu
Org. Lett., 2022, 24, 8218-8222. 10.1021/acs.orglett.2c03327
Iridium-catalyzed C(sp3)–H Borylation Using Silyl-Bipyridine Pincer Ligands
Ryohei Kawazu, Takeru Torigoe, and Yoichiro Kuninobu
Angew. Chem. Int. Ed., 2022, 61, e202202327. 10.1002/anie.202202327
Control of Site-Selectivity in Hydrogen Atom Transfer by Electrostatic Interaction: Proximal-Selective C(sp3)–H Alkylation of 2-Methylanilinium Salts Using a Decatungstate Photocatalyst
Jialin Zeng, Takeru Torigoe, and Yoichiro Kuninobu
ACS Catal., 2022, 12, 3058-3062. 10.1021/acscatal.2c00278
[Commentary]
歪みのないC(sp3)–Si結合の酸化的付加
鳥越尊
Organometallic News, 2021, 88.
Intramolecular Addition of a Dimethylamino C(sp3)–H Bond across C–C Triple Bonds using IrCL(DTBM-SEGPHOS)(ethylene) Catalyst: Synthesis of Indoles from 2-Alkynyl-N-methylanilines
Toshimichi Ohmura, Kaito Yagi, Takeru Torigoe, Michinori Suginome
Synthesis, 2021, 53, 3057-3064. 10.1055/a-1511-1025
Regioselective C–H Trifluoromethylation of Aromatic Compounds by Inclusion in Cyclodextrins
Xu Lu, Ryohei Kawazu, Jizhou Song, Yusuke Yoshigoe, Takeru Torigoe, and Yoichiro Kuninobu
Org. Lett., 2021, 23, 4327-4331. 10.1021/acs.orglett.1c01259
Manganese/Bipyridine-catalyzed Non-directed C(sp3)-H Bromination Using NBS and TMSN3
Kumar Sneh, Takeru Torigoe, Yoichiro Kuninobu
Beilstein J. Org. Chem., 2021, 17, 885-890. 10.3762/bjoc.17.74
Regioselective C(sp3)–H Alkylation of Fructopyranose Derivative by 1,6 HAT
Yanru Li, Shoto Miyamoto, Takeru Torigoe, Yoichiro Kuninobu
Org. Biomol. Chem., 2021, 19, 3124-3127. 10.1039/D1OB00326G
Urea-accelerated Iridium-catalyzed 2-Position-selective C-H Borylation of Indole Derivatives
Jie Wang, Takeru Torigoe, Yoichiro Kuninobu
Chem. Lett., 2021, 50, 808-811. 10.1246/cl.200939
[Review]
Regioselective C-H Trifluoromethylation of Heteroaromatic Compounds
Yoichiro Kuninobu, Takeru Torigoe
Bull. Chem. Soc. Jpn., 2021, 94, 532-541. 10.1246/bcsj.20200302
[Commentary]
有機溶媒がいらない!? －固体状態での高効率クロスカップリング反応
鳥越尊, 國信洋一郎
化学, 2020, 75, 64-65.
[Review]
Resent Progress on Transition Metal-catalysed Regioselective C–H Transformations Based on Noncovalent Interactions
Yoichiro Kuninobu, Takeru Torigoe
Org. Biomol. Chem., 2020, 18, 4126-4134. 10.1039/D0OB00703J
Iridium-Catalyzed ortho-C–H Borylation of Thioanisole Derivatives Using Bipyridine-Type Ligand
Jialin Zeng, Morio Naito, Takeru Torigoe, Masahiro Yamanaka, and Yoichiro Kuninobu
Org. Lett., 2020, 22, 3485-3489. 10.1021/acs.orglett.0c00946
Copper-Catalyzed Tertiary Alkylative Cyanation for the Synthesis of Cyanated Peptide Building Blocks
Naoki Miwa, Chihiro Tanaka, Syo Ishida, Goki Hirata, Jizhou Song, Takeru Torigoe, Yoichiro Kuninobu, Takashi Nishikata
J. Am. Chem. Soc., 2020, 142, 1692-1697. 10.1021/jacs.9b11349
Iridium-Catalyzed C(sp3)–H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans
Toshimichi Ohmura, Satoshi Kusaka, Takeru Torigoe, Michinori Suginome
Adv. Synth. Catal., 2019, 361, 4448-4453. 10.1002/adsc.201900749
2-Position-Selective Trifluoromethylthiolation of Six-Membered Heteroaromatic Compounds
Ryuhei Muta, Takeru Torigoe, Yoichiro Kuninobu
Org. Lett., 2019, 21, 4289-4292. 10.1021/acs.orglett.9b01474
Hydrogen-Bond-Controlled Formal Meta-Selective C–H Transformations and Regioselective Synthesis of Multisubstituted Aromatic Compounds
Jie Wang, Takeru Torigoe, Yoichiro Kuninobu
Org. Lett., 2019, 21, 1342-1346. 10.1021/acs.orglett.9b00030
Asymmetric Cycloisomerization of o-Alkenyl-N-methylanilines to Indolines through Iridium-Catalyzed C(sp3)–H Addition to Carbon–Carbon Double Bonds
Takeru Torigoe, Toshimichi Ohmura, Michinori Suginome
Angew. Chem. Int. Ed., 2017, 56, 14272–14276. 10.1002/anie.201708578
Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)–H Borylation at the Methyl Group on Silicon
Takeru Torigoe, Toshimichi Ohmura, Michinori Suginome
J. Org. Chem., 2017, 82, 2943–2956. 10.1021/acs.joc.6b02917
Iridium-Catalyzed Intramolecular Methoxy C–H Addition to Carbon–Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes
Takeru Torigoe, Toshimichi Ohmura, Michinori Suginome
Chem. Eur. J., 2016, 22, 10415–10419. 10.1002/chem.201602152
A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp3)–H Borylation and Conversion to Functionalized Siloxanes
Toshimichi Ohmura, Ikuo Sasaki, Takeru Torigoe, Michinori Suginome
Organometallics, 2016, 35, 1601–1603. 10.1021/acs.organomet.6b00316
Iridium-Catalysed Borylation of Sterically Hindered C(sp3)–H bonds: Remarkable Rate Acceleration by a Catalytic Amount of Potassium tert-Butoxide
Toshimichi Ohmura, Takeru Torigoe, Michinori Suginome
Chem. Commun., 2014, 50, 6333–6336. 10.1039/C4CC01262C
Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium Catalyzed C(sp3)–H Borylation
Toshimichi Ohmura, Takeru Torigoe, Michinori Suginome
Organometallics, 2013, 32, 6170–6173. 10.1021/om400900z
Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes
Toshimichi Ohmura, Takeru Torigoe, Michinori Suginome
J. Am. Chem. Soc., 2012, 134, 17416–17419. 10.1021/ja307956w
